Catalytic enantioselective Baylis-Hillman reactions. Correlation between pressure and enantiomeric excess

被引：153

作者：

Marko, IE

Giles, PR

Hindley, NJ

机构：

[1] Univ.́ Catholique de Louvain, Département de Chimie, Laboratoire de Chimie Organique, B-1348 Louvain-la-Neuve, Place Louis Pasteur I

来源：

TETRAHEDRON | 1997年 / 53卷 / 03期

关键词：

D O I：

10.1016/S0040-4020(96)01001-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several chiral amino-alcohols induce asymmetry in the Baylis-Hillman condensation of aldehydes with methyl vinyl ketone. Pressure plays an interesting role in this reaction. A model accounting for the pressure effect and rationalising the observed absolute stereochemistry is discussed. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：1015 / 1024

页数：10

共 34 条

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