A dynamic, isocyanurate-functionalized porous coordination polymer

被引：148

作者：

Ghosh, Sujit K. ^{[1
,2
]}

Bureekaew, Sareeya ^{[1
,2
]}

Kitagawa, Susumu ^{[1
,2
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, ERATO, Kitagawa Integrated Pore Project, Shimogyo Ku, Kyoto 6008813, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 18期

关键词：

adsorption; coordination polymers; hydrothermal synthesis; lanthanides; tripodal ligands;

D O I：

10.1002/anie.200705986

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Like a sponge: Soft, three-dimensional, porous coordination frameworks {[Ln-(tci)·H2O]•4H 2O}n (Ln=Ce, Gd; tciH3=tris(2-carboxyethyl) isocyanurate] were prepared from Ln(NO3)3·xH 2O and tciH3. The flexible arms and secondary functional groups of the ligand allow the framework to show spongelike dynamic behavior such as selective and stepwise adsorption, associated with single crystal to single crystal structural transformation (see scheme). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3403 / 3406

页数：4

共 41 条

[1]

[Anonymous], 2004, Angew. Chem, V116, P2388, DOI DOI 10.1016/j.jechem.2020.01.001

[2] Design, chirality, and flexibility in nanoporous molecule-based materials [J].

Bradshaw, D ;

Claridge, JB ;

Cussen, EJ ;

Prior, TJ ;

Rosseinsky, MJ .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :273-282

[3]

Chen B., 2005, ANGEW CHEM, V117, P4823, DOI DOI 10.1002/ange.200462787

[4] High H2 adsorption in a microporous metal-organic framework with open metal sites [J].

Chen, BL ;

Ockwig, NW ;

Millward, AR ;

Contreras, DS ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749

[5] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].

Cho, So-Hye ;

Ma, Baoqing ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. ;

Albrecht-Schmitt, Thomas E. .

CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565

[6] Microporous metal-organic frameworks incorporating 1,4-benzeneditetrazolate: Syntheses, structures, and hydrogen storage properties [J].

Dinca, Mircea ;

Yu, Anta F. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (27) :8904-8913

[7] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[8] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

[9] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[10] Flexibility in metal-organic framework materials: Impact on sorption properties [J].

Fletcher, AJ ;

Thomas, KM ;

Rosseinsky, MJ .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (08) :2491-2510

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