Determination of concentration and enantiomeric excess of amines and amino alcohols with a chiral nickel(II) complex

被引：46

作者：

He, Xuan ^{[1
]}

Zhang, Qi ^{[1
]}

Liu, Xiaohua ^{[1
]}

Lin, Lili ^{[1
]}

Feng, Xiaoming ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 42期

基金：

中国国家自然科学基金;

关键词：

HIGHLY ENANTIOSELECTIVE SYNTHESIS; INDICATOR-DISPLACEMENT ASSAYS; PATTERN-BASED RECOGNITION; CARBOXYLIC-ACIDS; FLUORESCENCE; CATALYSTS; FLUOROSENSOR; MOLECULES; IDENTITY; RECEPTOR;

D O I：

10.1039/c1cc14660b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral N,N'-dioxide-Ni(II) complex was found to exhibit highly enantioselective fluorescent recognition of chiral amines and amino alcohols. It can be used to determine their concentration and ee value. Using a 96-well plate, high-throughput screening for enantiomer discrimination was accomplished.

引用

收藏

页码：11641 / 11643

页数：3

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