A Battery Made from a Single Material

被引:331
作者
Han, Fudong [1 ]
Gao, Tao [1 ]
Zhu, Yujie [1 ]
Gaskell, Karen J. [2 ]
Wang, Chunsheng [1 ]
机构
[1] Univ Maryland, Dept Chem & Biomol Engn, College Pk, MD 20742 USA
[2] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA
基金
美国国家科学基金会;
关键词
STATE LITHIUM BATTERY; HIGH-CAPACITY; ION BATTERY; COMPOSITE ELECTRODE; CATHODE MATERIALS; SULFIDE; LI; PERFORMANCE; INTERFACE; LICOO2;
D O I
10.1002/adma.201500180
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A single-material battery is prepared using Li10GeP2S12 as the electrolyte, anode, and cathode, based on the Li-S and Ge-S components in Li10GeP2S12 acting as the active centers for its cathode and anode performance, respectively. The single-Li10GeP2S12 battery exhibits a remarkably low interfacial resistance due to the improvement of interfacial contact and interactions, and the suppression of interfacial strain/stress.
引用
收藏
页码:3473 / 3483
页数:11
相关论文
共 63 条
[1]   A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries [J].
Aboulaich, Abelmaula ;
Bouchet, Renaud ;
Delaizir, Gaelle ;
Seznec, Vincent ;
Tortet, Laurence ;
Morcrette, Mathieu ;
Rozier, Patrick ;
Tarascon, Jean-Marie ;
Viallet, Virginie ;
Dolle, Mickael .
ADVANCED ENERGY MATERIALS, 2011, 1 (02) :179-183
[2]   Thin-film lithium and lithium-ion batteries [J].
Bates, JB ;
Dudney, NJ ;
Neudecker, B ;
Ueda, A ;
Evans, CD .
SOLID STATE IONICS, 2000, 135 (1-4) :33-45
[3]   Electrolytic stability limit and rapid lithium insertion in the fast-ion-conducting Li0.29La0.57TiO3 perovskite-type compound [J].
Birke, P ;
Scharner, S ;
Huggins, RA ;
Weppner, W .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) :L167-L169
[4]   A first approach to a monolithic all solid state inorganic lithium battery [J].
Birke, P ;
Salam, F ;
Döring, S ;
Weppner, W .
SOLID STATE IONICS, 1999, 118 (1-2) :149-157
[5]   Electrochemical properties of all-solid-state lithium secondary batteries using Li-argyrodite Li6PS5Cl as solid electrolyte [J].
Boulineau, Sylvain ;
Tarascon, Jean-Marie ;
Leriche, Jean-Bernard ;
Viallet, Virginie .
SOLID STATE IONICS, 2013, 242 :45-48
[6]   High performance silicon-based anodes in solid-state lithium batteries [J].
Cervera, Rinlee B. ;
Suzuki, Naoki ;
Ohnishi, Tsuyoshi ;
Osada, Minoru ;
Mitsuishi, Kazutaka ;
Kambara, Takayoshi ;
Takada, Kazunori .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (02) :662-666
[7]   High capacity and cyclic performance in a three-dimensional composite electrode filled with inorganic solid electrolyte [J].
Chen, Kai ;
Shen, Yang ;
Zhang, Yibo ;
Lin, Yuanhua ;
Nan, Ce-Wen .
JOURNAL OF POWER SOURCES, 2014, 249 :306-310
[8]   Germanium sulfide(II and IV) nanoparticles for enhanced performance of lithium ion batteries [J].
Cho, Yong Jae ;
Im, Hyung Soon ;
Myung, Yoon ;
Kim, Chang Hyun ;
Kim, Han Sung ;
Back, Seung Hyuk ;
Lim, Young Rok ;
Jung, Chan Su ;
Jang, Dong Myung ;
Park, Jeunghee ;
Cha, Eun Hee ;
Choo, Sung Ho ;
Song, Min Seob ;
Cho, Won Il .
CHEMICAL COMMUNICATIONS, 2013, 49 (41) :4661-4663
[9]   The Stone Age Revisited: Building a Monolithic Inorganic Lithium-Ion Battery [J].
Delaizir, Gaelle ;
Viallet, Virginie ;
Aboulaich, Abdelmaula ;
Bouchet, Renaud ;
Tortet, Laurence ;
Seznec, Vincent ;
Morcrette, Mathieu ;
Tarascon, Jean-Marie ;
Rozier, Patrick ;
Dolle, Mickael .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (10) :2140-2147
[10]   SOLID-STATE LITHIUM BATTERY - NEW IMPROVED CHEMICAL POWER SOURCE FOR IMPLANTABLE CARDIAC PACEMAKERS [J].
GREATBATCH, W ;
LEE, JH ;
MATHIAS, W ;
ELDRIDGE, M ;
MOSER, JR ;
SCHNEIDER, AA .
IEEE TRANSACTIONS ON BIOMEDICAL ENGINEERING, 1971, BM18 (05) :317-+