H2 Activation -: Heterolytic H2 activation by nonmetals

被引：157

作者：

Kenward, Alyson L. ^{[1
]}

Piers, Warren E. ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 01期

关键词：

carbenes; hydrogen; Lewis acids; Lewis bases; main-group elements;

D O I：

10.1002/anie.200702816

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Nice cleavage: Two new strategies for the transition-metal-free activation of σ bonds are presented, namely, Bertrand's activation of dihydrogen by carbenes (see picture, left) and Stephan's frustrated" Lewis acid/base pairs (right; R = Me 3C6H2). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：38 / 41

页数：4

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