An electrochromic and fluorescent polymer based on 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole

被引：63

作者：

Cihaner, Atilla ^{[1
]}

Algi, Fatih ^{[2
]}

机构：

[1] Atilim Univ, Chem Grp, Fac Engn, TR-06836 Ankara, Turkey

[2] Canakkale Onsekiz Mart Univ, Dept Chem, TR-17100 Canakkale, Turkey

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2008年 / 614卷 / 1-2期

关键词：

electrochemical polymerization; polythiophene; polypyrrole; naphthalene;

D O I：

10.1016/j.jelechem.2007.11.024

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel polymer was synthesized by electrochemical polymerization of 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole (SNS-1-NAPH). The corresponding polymer (PSNS-1-NAPH) was characterized by cyclic voltammetry, FT-IR and UV-vis spectroscopy. The polymer has a very well-defined and reversible redox process in both organic and aqueous solutions. Furthermore, it shows stable electrochromic behavior; yellow in the neutral state, green in the intermediate state and violet in the oxidized state. PSNS-1-NAPH is soluble in common solvents. Although SNS-1-NAPH is almost nonfluorescent, its polymer is a yellow and/or green light emitter. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：101 / 106

页数：6

共 45 条

[31] Synthesis and characterization of a new soluble conducting polymer and its electrochromic devices [J].

Sahin, Elif ;

Sahmetlioglu, Ertugrul ;

Akhmedov, Idris M. ;

Tanyeli, Cihangir ;

Toppare, Levent .

ORGANIC ELECTRONICS, 2006, 7 (05) :351-362

[32] ELECTROCHEMICAL PREPARATION OF CONDUCTING POLY(3-METHYLTHIOPHENE) - COMPARISON WITH POLYTHIOPHENE AND POLY(3-ETHYLTHIOPHENE) [J].

SATO, M ;

TANAKA, S ;

KAERIYAMA, K .

SYNTHETIC METALS, 1986, 14 (04) :279-288

[33] Strategies towards functionalised electronically conducting organic copolymers [J].

Schweiger, LF ;

Ryder, KS ;

Morris, DG ;

Glidle, A ;

Cooper, JM .

JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (01) :107-114

[34]

Skotheim T.A., 1998, Handbook of Conducting Polymer

[35] Electrochromic properties of a soluble conducting polymer of 1-benzyl-2,5-di(thiophene-2-yl)-1H-pyrrole [J].

Tarkuc, S. ;

Sahmetlioglu, E. ;

Tanyeh, C. ;

Akhmedov, I. M. ;

Toppare, L. .

SENSORS AND ACTUATORS B-CHEMICAL, 2007, 121 (02) :622-628

[36] A soluble conducting polymer: 1-phenyl-2,5-di(2-thienyl)-1H-pyrrole and its electrochromic application [J].

Tarkuc, S. ;

Sahmetlioglu, E. ;

Tanyeli, C. ;

Akhmedov, I. M. ;

Toppare, L. .

ELECTROCHIMICA ACTA, 2006, 51 (25) :5412-5419

[37] POLY(3-METHYLTHIOPHENE)-COATED ELECTRODES - OPTICAL AND ELECTRICAL-PROPERTIES AS A FUNCTION OF REDOX POTENTIAL AND AMPLIFICATION OF ELECTRICAL AND CHEMICAL SIGNALS USING POLY(3-METHYLTHIOPHENE)-BASED MICROELECTROCHEMICAL TRANSISTORS [J].

THACKERAY, JW ;

WHITE, HS ;

WRIGHTON, MS .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (23) :5133-5140

[38] POLYTHIOPHENE FIELD-EFFECT TRANSISTOR - ITS CHARACTERISTICS AND OPERATION MECHANISM [J].

TSUMURA, A ;

KOEZUKA, H ;

ANDO, T .

SYNTHETIC METALS, 1988, 25 (01) :11-23

[39] A novel multielectrochromic copolymer based on 1-(4-nitrophenyl)-2,5-di(2-thienyl)-1H-pyrrole and EDOT [J].

Varis, Serhat ;

Ak, Metin ;

Akhmedov, Iris M. ;

Tanyeli, Cihangir ;

Toppare, Levent .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 603 (01) :8-14

[40] Synthesis and characterization of a new soluble conducting polymer and its electrochromic device [J].

Varis, Serhat ;

Ak, Metin ;

Tanyeli, Cihangir ;

Akhmedov, Idris Mecidoglu ;

Toppare, Levent .

SOLID STATE SCIENCES, 2006, 8 (12) :1477-1483

← 1 2 3 4 5 →