Cascade Catalysis for the Homogeneous Hydrogenation of CO2 to Methanol

被引：486

作者：

Huff, Chelsea A. ^{[1
]}

Sanford, Melanie S. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 45期

关键词：

N-HETEROCYCLIC CARBENE; FRUSTRATED LEWIS PAIRS; CARBON-DIOXIDE; REDUCTION; CONVERSION; ALCOHOLS; HYDROGENOLYSIS; COMPLEXES; FORMATES; AMMONIA;

D O I：

10.1021/ja208760j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication demonstrates the homogeneous hydrogenation of CO2 to CH3OH via cascade catalysis. Three different homogeneous catalysts, (PMe3)(4)Ru(Cl)(OAc), Sc(OTf)(3), and (PNN)Ru(CO)(H), operate in sequence to promote this transformation.

引用

页码：18122 / 18125

页数：4

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