Molecular catalysts for water oxidation

被引：590

作者：

Yagi, M

Kaneko, M ^{[1
]}

机构：

[1] Niigata Univ, Fac Educ & Human Sci, Niigata 9502181, Japan

[2] Ibaraki Univ, Fac Sci, Mito, Ibaraki 3108512, Japan

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 01期

关键词：

D O I：

10.1021/cr980108l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular aspects and activities of water oxidation catalysts are reviewed. The structure and catalytic mechanism of photosynthesis is explained with reference to photosynthetic oxygen-evolving center. Catalytic activity in heterogeneous and homogeneous systems are summarized. Artificial photosystem model to induce water oxidation is also analyzed. The study suggests stabilization of molecular catalysts by intermolecular decomposition.

引用

收藏

页码：21 / 35

页数：15

相关论文

共 114 条

[31] PHOTOCATALYTIC ACTIVITY OF ALKALI-METAL TITANATES COMBINED WITH RU IN THE DECOMPOSITION OF WATER [J].

INOUE, Y ;

KUBOKAWA, T ;

SATO, K .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (10) :4059-4063

[32]

KANEKO M, 1991, MACROMOLECULAR COMPL

[33]

KANEKO M, 1976, 11TH S UNS PROBL POL, P21

[34]

KANEKO M, 1997, ORGANIC CONDUCTIVE M, V4

[35] Photocatalytic decomposition of pure water into H2 and O2 over SrTa2O6 prepared by a flux method [J].

Kato, H ;

Kudo, A .

CHEMISTRY LETTERS, 1999, (11) :1207-1208

[36] New tantalate photocatalysts for water decomposition into H2 and O2 [J].

Kato, H ;

Kudo, A .

CHEMICAL PHYSICS LETTERS, 1998, 295 (5-6) :487-492

[37] A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting [J].

Khaselev, O ;

Turner, JA .

SCIENCE, 1998, 280 (5362) :425-427

[38] Enhancing effects of amino acid residue model compounds on catalytic activity of an artificial oxygen evolving center [J].

Kinoshita, K ;

Yagi, M ;

Kaneko, M .

MACROMOLECULES, 1998, 31 (18) :6042-6045

[39] Activity analysis of mononuclear ruthenium ammine complex dispersed in a polymer membrane as an electrochemical water oxidation catalyst [J].

Kinoshita, K ;

Yagi, M ;

Kaneko, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 142 (01) :1-5

[40] Visible light induced photo-oxidation of water. Formation of intermediary hydroxyl radicals through the photoexcited triplet state of perfluorophenazine [J].

Kitamura, T ;

Fudemoto, H ;

Wada, Y ;

Murakoshi, K ;

Kusaba, M ;

Nakashima, N ;

Majima, T ;

Yanagida, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (02) :221-229

← 1 2 3 4 5 6 7 8 9 10 →