Molecular catalysts for water oxidation

被引：590

作者：

Yagi, M

Kaneko, M ^{[1
]}

机构：

[1] Niigata Univ, Fac Educ & Human Sci, Niigata 9502181, Japan

[2] Ibaraki Univ, Fac Sci, Mito, Ibaraki 3108512, Japan

来源：

CHEMICAL REVIEWS | 2001年 / 101卷 / 01期

关键词：

D O I：

10.1021/cr980108l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular aspects and activities of water oxidation catalysts are reviewed. The structure and catalytic mechanism of photosynthesis is explained with reference to photosynthetic oxygen-evolving center. Catalytic activity in heterogeneous and homogeneous systems are summarized. Artificial photosystem model to induce water oxidation is also analyzed. The study suggests stabilization of molecular catalysts by intermolecular decomposition.

引用

收藏

页码：21 / 35

页数：15

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