Synthesis, characterization and X-ray crystal structures of lithium coordination polymer from cyclobutane-1,1-dicarboxylic acid

被引:8
作者
Chen, Zhi
Fei, Zhaofu
Zhao, Dongbin
Feng, Yujun
Yu, Kaibei
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Ecole Polytech Fed Lausanne, BCH, Swiss Fed Inst Technol, CH-1015 Lausanne, Switzerland
[4] Chengdu Ctr Anal & Testing, Chengdu 610041, Peoples R China
关键词
coordination polymer; lithium salt; crystal structure; TGA analysis;
D O I
10.1016/j.inoche.2006.09.013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel lithium salt, cyclobutane-1,1-dicarboxylic lithium was synthesized and characterized by NMR, IR, ESI-MS, X-ray single crystal analysis, and TG/DTG (TGA) thermal analysis. The crystal structure information reveals the coordination polymer nature and ESI-MS shows its aggregation behavior in aqueous solution. TGA analysis discloses the CO2 release with respect to temperature rise. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:77 / 79
页数:3
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