Stability improvement of Cu3(BTC)2 metal-organic frameworks under steaming conditions by encapsulation of a Keggin polyoxometalate

被引：98

作者：

Mustafa, Danilo ^{[1
]}

Breynaert, Eric ^{[1
]}

Bajpe, Sneha R. ^{[1
]}

Martens, Johan A. ^{[1
]}

Kirschhock, Christine E. A. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Microbial & Mol Syst, Ctr Surface Chem & Catalysis, B-3000 Louvain, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期

关键词：

HIGH-CAPACITY; DIRECT GROWTH; ADSORPTION; HYDROGEN; STORAGE; DIFFUSION; FILMS; OXIDE;

D O I：

10.1039/c1cc12341f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cu-3(BTC)(2) with an incorporated Keggin polyoxometalate was demonstrated to be stable under steaming conditions up to 483 K, while the isostructural HKUST-1 degrades and transforms into [Cu2OH(BTC)(H2O)](n)center dot 2nH(2)O from 343 K onwards.

引用

页码：8037 / 8039

页数：3

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