Rotaxanes as ligands: from molecules to materials

被引：278

作者：

Loeb, Stephen J. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL SOCIETY REVIEWS | 2007年 / 36卷 / 02期

关键词：

D O I：

10.1039/b605172n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review documents the discovery and application of the supramolecular template (1,2-bis(pyridinium) ethane),(24-crown-8) for preparing interlocked molecules. Focus is on the supramolecular chemistry of the pseudorotaxanes formed with various pyridinium axles and crown ether wheels and how this particular class of mechanically linked molecule has been (i) used to construct rudimentary molecular machines such as molecular shuttles and flip switches, (ii) used as ligands for coordination chemistry and (iii) used to create metal-organic framework (MORF) materials.

引用

页码：226 / 235

页数：10

共 43 条

[11] Channels and cavities lined with interlocked components: Metal-based polyrotaxanes that utilize pyridinimn axles and crown ether wheels as ligands [J].

Davidson, GJE ;

Loeb, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (01) :74-77

[12] Zwitterionic [2]rotaxanes utilising anionic transition metal stoppers [J].

Davidson, GJE ;

Loeb, SJ ;

Parekh, NA ;

Wisner, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (21) :3135-3136

[13] An acid-base switchable [2]rotaxane [J].

Elizarov, AM ;

Chiu, SH ;

Stoddart, JF .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (26) :9175-9181

[14] [2]rotaxanes containing pyridinium-phosphonium axles and 24-crown-8 ether wheels [J].

Georges, N ;

Loeb, SJ ;

Tiburcio, J ;

Wisner, JA .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2004, 2 (19) :2751-2756

[15] Polyamide pseudorotaxanes, rotaxanes, and catenanes based on bis(5-carboxy-1,3-phenylene)-(3x+2)-crown-x ethers [J].

Gibson, HW ;

Nagvekar, DS ;

Yamaguchi, N ;

Bhattacharjee, S ;

Wang, H ;

Vergne, MJ ;

Hercules, DM .

MACROMOLECULES, 2004, 37 (20) :7514-7529

[16] The missing link: A 2D metal-organic rotaxane framework (MORF) with one rotaxane linker and one naked linker [J].

Hoffart, Dennis J. ;

Loeb, Stephen J. .

SUPRAMOLECULAR CHEMISTRY, 2007, 19 (1-2) :89-93

[17] Metal-organic rotaxane frameworks:: Three-dimensional polyrotaxanes from lanthanide-ion nodes, pyridinium N-oxide axles, and crown-ether wheels [J].

Hoffart, DJ ;

Loeb, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (06) :901-904

[18]

HOFFART DJ, 2004, THESIS U WINDSOR WIN

[19] Polypseudorotaxanes and polyrotaxanes [J].

Huang, FH ;

Gibson, HW .

PROGRESS IN POLYMER SCIENCE, 2005, 30 (10) :982-1018

[20] Host-guest interactions template: the synthesis of a [3]catenane [J].

Hubbard, AL ;

Davidson, GJE ;

Patel, RH ;

Wisner, JA ;

Loeb, SJ .

CHEMICAL COMMUNICATIONS, 2004, (02) :138-139

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