Rotaxanes as ligands: from molecules to materials

被引：281

作者：

Loeb, Stephen J. ^{[1
]}

机构：

[1] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL SOCIETY REVIEWS | 2007年 / 36卷 / 02期

关键词：

D O I：

10.1039/b605172n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This tutorial review documents the discovery and application of the supramolecular template (1,2-bis(pyridinium) ethane),(24-crown-8) for preparing interlocked molecules. Focus is on the supramolecular chemistry of the pseudorotaxanes formed with various pyridinium axles and crown ether wheels and how this particular class of mechanically linked molecule has been (i) used to construct rudimentary molecular machines such as molecular shuttles and flip switches, (ii) used as ligands for coordination chemistry and (iii) used to create metal-organic framework (MORF) materials.

引用

页码：226 / 235

页数：10

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