Coordination complexes of bis(amido)cyclodiphosph(III/V and V/V)azane imides and chalcogenides

被引：92

作者：

Briand, GG ^{[1
]}

Chivers, T ^{[1
]}

Krahn, M ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2002年 / 233卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

cyclodiphosph(III/V)azane; cyclodiphosph(V/V)azane; imidometaphosphates; coordination compounds; chalcogens; ambidentate ligands;

D O I：

10.1016/S0010-8545(02)00033-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metaphosphates with imido and chalcogenido substituents attached to a central phosphorus(V) center form ambidentate dimeric dianions that are potential components of metal-containing coordination polymers. This review summarizes the syntheses and structures of s-, p- and d-block metal complexes of these versatile ligands and their bis(amido)cyclodiphosph(V/V)azane precursors. The synthesis and structures of metal complexes of the corresponding cyclodiphosph(III/V)azane ligands are also discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：237 / 254

页数：18

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