A metal-organic framework via the reaction of benzoate with a cationic inorganic material

被引：5

作者：

Swanson, Claudia H. ^{[1
]}

Cummings, Steven P. ^{[1
]}

Grysell, Martin ^{[1
]}

Tran, Dat T. ^{[1
]}

Rogow, David L. ^{[1
]}

Oliver, Allen G. ^{[1
]}

Oliver, Scott R. J. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

DALTON TRANSACTIONS | 2009年 / 44期

关键词：

CRYSTAL-STRUCTURE; COORDINATION POLYMER; ADSORPTION; HYDROGEN; SITES; COMPLEXES; CATALYSIS;

D O I：

10.1039/b912874c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Our research group previously reported a two-dimensional cationic inorganic material (BING-5, Pb3F5NO3) where nitrate resides in the interlamellar space and can be anion exchanged. Investigation of the possible exchange of nitrate for benzoate led to the discovery of a layered metal-organic framework, lead benzoate hydrate [Pb(C6H5CO2)(2)(OH2)]. The compound crystallizes as colourless plates in the monoclinic space group P2(1)/c. The two dimensional lead-oxygen layers contain bridging benzoate oxygen atoms, with bridging water molecules further supporting the layers. The benzoate molecules are positioned perpendicular to the layers and form a hydrophobic bilayer region. The material shows basic character when immersed in various solvents suggesting potential as a base catalyst.

引用

页码：9849 / 9853

页数：5

共 33 条

[11]

Evanhoe R, 2006, CHEM ENG NEWS, V84, P38, DOI 10.1021/cen-v084n026.p038

[12]

GAU HM, 1992, ABSTR PAP AM CHEM SO, V203

[13] A NEW SYNTHETIC APPROACH TO THE FERRITIN CORE UNCOVERS THE SOLUBLE IRON(III) OXO-HYDROXO AGGREGATE [FE11O6(OH)6(O2CPH)15] [J].

GORUN, SM ;

LIPPARD, SJ .

NATURE, 1986, 319 (6055) :666-668

[14] A lanthanide metal-organic framework with high thermal stability and available Lewis-acid metal sites [J].

Guo, Xiaodan ;

Zhu, Guangshan ;

Li, Zhongyue ;

Sun, Fuxing ;

Yang, Zhenghong ;

Qiu, Shilun .

CHEMICAL COMMUNICATIONS, 2006, (30) :3172-3174

[15] Adsorption of 2,4-D and carbofuran pesticides using fertilizer and steel industry wastes [J].

Gupta, Vinod K. ;

Ali, Imran ;

Suhas ;

Saini, Vipin K. .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 299 (02) :556-563

[16] CATENA-BIS(MU-BENZOATO-O,O',MU-O)-BIS(PYRIDINE)-DISILVER(I), [AG2(C5H5N)2(C7H5O2)2] [J].

HEDRICH, M ;

HARTL, H .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (MAY) :533-536

[17]

HEWAT P, 2007, INORGANIC CRYSTAL ST

[18] Adsorption of MCPA pesticide by MgAl-layered double hydroxides [J].

Inacio, J ;

Taviot-Guého, C ;

Forano, C ;

Besse, JP .

APPLIED CLAY SCIENCE, 2001, 18 (5-6) :255-264

[19] Metal-organic frameworks [J].

James, SL .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288

[20] MAGNETOSTRUCTURAL CORRELATION IN DIMERIC COPPER(II) BENZOATES [J].

KAWATA, T ;

UEKUSA, H ;

OHBA, S ;

FURUKAWA, T ;

TOKII, T ;

MUTO, Y ;

KATO, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1992, 48 :253-261

← 1 2 3 4 →