A metal-organic framework via the reaction of benzoate with a cationic inorganic material

被引：5

作者：

Swanson, Claudia H. ^{[1
]}

Cummings, Steven P. ^{[1
]}

Grysell, Martin ^{[1
]}

Tran, Dat T. ^{[1
]}

Rogow, David L. ^{[1
]}

Oliver, Allen G. ^{[1
]}

Oliver, Scott R. J. ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

DALTON TRANSACTIONS | 2009年 / 44期

关键词：

CRYSTAL-STRUCTURE; COORDINATION POLYMER; ADSORPTION; HYDROGEN; SITES; COMPLEXES; CATALYSIS;

D O I：

10.1039/b912874c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Our research group previously reported a two-dimensional cationic inorganic material (BING-5, Pb3F5NO3) where nitrate resides in the interlamellar space and can be anion exchanged. Investigation of the possible exchange of nitrate for benzoate led to the discovery of a layered metal-organic framework, lead benzoate hydrate [Pb(C6H5CO2)(2)(OH2)]. The compound crystallizes as colourless plates in the monoclinic space group P2(1)/c. The two dimensional lead-oxygen layers contain bridging benzoate oxygen atoms, with bridging water molecules further supporting the layers. The benzoate molecules are positioned perpendicular to the layers and form a hydrophobic bilayer region. The material shows basic character when immersed in various solvents suggesting potential as a base catalyst.

引用

页码：9849 / 9853

页数：5

共 33 条

[21] CRYSTAL STRUCTURE OF CUPRIC BENZOATE TRIHYDRATE CU (C6H5COO)23H2O [J].

KOIZUMI, H ;

OSAKI, K ;

WATANABE, T .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1963, 18 (01) :117-&

[22] Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter [J].

Park, Young Kwan ;

Choi, Sang Beom ;

Kim, Hyunuk ;

Kim, Kimoon ;

Won, Byoung-Ho ;

Choi, Kihang ;

Choi, Jung-Sik ;

Ahn, Wha-Seung ;

Won, Nayoun ;

Kim, Sungjee ;

Jung, Dong Hyun ;

Choi, Seung-Hoon ;

Kim, Ghyung-Hwa ;

Cha, Sun-Shin ;

Jhon, Young Ho ;

Yang, Jin Kuk ;

Kim, Jaheon .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (43) :8230-8233

[23] Disordered structure of polymeric bismuth tribenzoate, [Bi(C6H5COO)3]n [J].

Rae, AD ;

Gainsford, GJ ;

Kemmitt, T .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 :438-442

[24] ANTIMONYTRIBENZOATE [J].

ROSMANN, D ;

HUBLER, K ;

SCHMIDT, A .

MONATSHEFTE FUR CHEMIE, 1995, 126 (10) :1045-1050

[25]

Sauer F., 1973, SPECIAL REPORT NEW Y, P22

[26] Triaquabenzoatocalcium(II) monobenzoate: coordination polymer chains linked into a two-dimensional framework by hydrogen bonds [J].

Senkovska, I ;

Thewalt, U .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 :M448-M449

[27] Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction [J].

Spencer, EC ;

Howard, JAK ;

McIntyre, GJ ;

Rowsell, JLC ;

Yaghi, OM .

CHEMICAL COMMUNICATIONS, 2006, (03) :278-280

[28]

SPOHN M, 1986, Z NATURFORSCH B, V41, P1373

[29]

SPOHN M, 1988, Z NATURFORSCH B, V43, P540

[30]

STASOVA, 1959, KRISTALLOGRAFIYA, V4, P243

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