High Temperature-Stable Perovskite Solar Cell Based on Low-Cost Carbon Nanotube Hole Contact

被引：197

作者：

Aitola, Kerttu ^{[1
]}

Domanski, Konrad ^{[2
]}

Correa-Baena, Juan-Pablo ^{[3
]}

Sveinbjornsson, Kari ^{[1
]}

Saliba, Michael ^{[2
]}

Abate, Antonio ^{[4
]}

Graetzel, Michael ^{[2
]}

Kauppinen, Esko ^{[5
]}

Johansson, Erik M. J. ^{[1
]}

Tress, Wolfgang ^{[2
]}

Hagfeldt, Anders ^{[6
]}

Boschloo, Gerrit ^{[1
]}

机构：

[1] Uppsala Univ, Dept Chem, Angstrom Lab, Phys Chem, Box 523, S-75120 Uppsala, Sweden

[2] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

[3] MIT, 77 Massachusetts Ave, Cambridge, MA 02139 USA

[4] Univ Fribourg, Adolphe Merkle Inst, CH-1700 Fribourg, Switzerland

[5] Aalto Univ, Dept Appl Phys, POB 15100, Aalto 00076, Finland

[6] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photomol Sci, CH-1015 Lausanne, Switzerland

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 17期

基金：

瑞士国家科学基金会; 瑞典研究理事会;

关键词：

CONDUCTOR-FREE; DEGRADATION; EXTRACTION; NETWORKS;

D O I：

10.1002/adma.201606398

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mixed ion perovskite solar cells (PSC) are manufactured with a metal-free hole contact based on press-transferred single-walled carbon nanotube (SWCNT) film infiltrated with 2,2,7,-7-tetrakis(N, N-di-p-methoxyphenylamine)-9,90-spirobifluorene (Spiro-OMeTAD). By means of maximum power point tracking, their stabilities are compared with those of standard PSCs employing spin-coated Spiro-OMeTAD and a thermally evaporated Au back contact, under full 1 sun illumination, at 60 degrees C, and in a N-2 atmosphere. During the 140 h experiment, the solar cells with the Au electrode experience a dramatic, irreversible efficiency loss, rendering them effectively nonoperational, whereas the SWCNT-contacted devices show only a small linear efficiency loss with an extrapolated lifetime of 580 h.

引用

页数：5

共 21 条

[1] Carbon nanotube-based hybrid hole-transporting material and selective contact for high efficiency perovskite solar cells [J].

Aitola, Kerttu ;

Sveinbjornsson, Kari ;

Correa-Baena, Juan-Pablo ;

Kaskela, Antti ;

Abate, Antonio ;

Tian, Ying ;

Johansson, Erik M. J. ;

Graetzel, Michael ;

Kauppinen, Esko I. ;

Hagfeldt, Anders ;

Boschloo, Gerrit .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (02) :461-466

[2] Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide [J].

Anaraki, Elham Halvani ;

Kermanpur, Ahmad ;

Steier, Ludmilla ;

Domanski, Konrad ;

Matsui, Taisuke ;

Tress, Wolfgang ;

Saliba, Michael ;

Abate, Antonio ;

Gratzel, Michael ;

Hagfeldt, Anders ;

Correa-Baena, Juan-Pablo .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (10) :3128-3134

[3]

[Anonymous], 1989, ENERGY ENV SCI

[4] Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite [J].

Conings, Bert ;

Drijkoningen, Jeroen ;

Gauquelin, Nicolas ;

Babayigit, Aslihan ;

D'Haen, Jan ;

D'Olieslaeger, Lien ;

Ethirajan, Anitha ;

Verbeeck, Jo ;

Manca, Jean ;

Mosconi, Edoardo ;

De Angelis, Filippo ;

Boyen, Hans-Gerd .

ADVANCED ENERGY MATERIALS, 2015, 5 (15)

[5] Unbroken Perovskite: Interplay of Morphology, Electro-optical Properties, and Ionic Movement [J].

Correa-Baena, Juan-Pablo ;

Anaya, Miguel ;

Lozano, Gabriel ;

Tress, Wolfgang ;

Domanski, Konrad ;

Saliba, Michael ;

Matsui, Taisuke ;

Jacobsson, Tor Jesper ;

Calvo, Mauricio E. ;

Abate, Antonio ;

Gratzel, Michael ;

Miguez, Hernan ;

Hagfeldt, Anders .

ADVANCED MATERIALS, 2016, 28 (25) :5031-5037

[6] Not All That Glitters Is Gold: Metal-Migration-Induced Degradation in Perovskite Solar Cells [J].

Domanski, Konrad ;

Correa-Baena, Juan-Pablo ;

Mine, Nicolas ;

Nazeeruddin, Mohammad Khaja ;

Abate, Antonio ;

Saliba, Michael ;

Tress, Wolfgang ;

Hagfeldt, Anders ;

Gratzel, Michael .

ACS NANO, 2016, 10 (06) :6306-6314

[7] Enhanced Hole Extraction in Perovskite Solar Cells Through Carbon Nanotubes [J].

Habisreutinger, Severin N. ;

Leijtens, Tomas ;

Eperon, Giles E. ;

Stranks, Samuel D. ;

Nicholas, Robin J. ;

Snaith, Henry J. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (23) :4207-4212

[8] Carbon Nanotube/Polymer Composites as a Highly Stable Hole Collection Layer in Perovskite Solar Cells [J].

Habisreutinger, Severin N. ;

Leijtens, Tomas ;

Eperon, Giles E. ;

Stranks, Samuel D. ;

Nicholas, Robin J. ;

Snaith, Henry J. .

NANO LETTERS, 2014, 14 (10) :5561-5568

[9] Efficient charge extraction and slow recombination in organic-inorganic perovskites capped with semiconducting single-walled carbon nanotubes [J].

Ihly, Rachelle ;

Dowgiallo, Anne-Marie ;

Yang, Mengjin ;

Schulz, Philip ;

Stanton, Noah J. ;

Reid, Obadiah G. ;

Ferguson, Andrew J. ;

Zhu, Kai ;

Berry, Joseph J. ;

Blackburn, Jeffrey L. .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (04) :1439-1449

[10]

Jeon N. J., 2014, NAT MATER, V13, P1, DOI DOI 10.1038/NMAT4014

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