A linear polymer manganese(III) complex;: synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)]-manganese(III)

被引：26

作者：

Zhang, KL

Xu, Y

Zheng, CG

Zhang, Y

Wang, Z

You, XZ ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2001年 / 318卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

manganese complexes; chain complexes; Schiff base complexes; crystal structures; magnetic properties;

D O I：

10.1016/S0020-1693(01)00417-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The X-ray structural analyses reveal that the title complex contains the Mn(saloph) [saloph = N,N ' -O-phenylenebis(salicylide-neaminato)] moieties bridged by single acetato groups in an anti-anti configuration to form linear polymer chains. Variable temperature magnetic susceptibility measurements (4.7-270 K) show the occurrence of very weak antiferromagnetic interactions between the Mn(III) ions with J = -1.32 cm(-1) and D = -0.72 cm(-1). (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：61 / 66

页数：6

共 33 条

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[12] CATALYTIC ASYMMETRIC OXIDATIONS USING OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES AS CATALYSTS [J].