Optically active palladacycles containing imines derived from 1-(1-naphthyl)ethylamine: new resolving agents for P-chiral phosphines

被引：54

作者：

Albert, J

Cadena, JM

Granell, JR

Solans, X

Font-Bardia, M

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

[2] Univ Barcelona, Dept Critallog Mineral & Diposits Mineral, E-08028 Barcelona, Spain

来源：

TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 09期

关键词：

D O I：

10.1016/S0957-4166(00)00143-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the new palladium metallacycles containing imines derived from 1-(1-naphthyl)ethylamine is reported. These new organometallic complexes have been used to resolve the P-chiral ligand benzylcyclohexylphenylphosphine. The absolute configuration of (R-C,S-P)-[PdCl{2[HC=N-CH(Me)C10H (6)]-3-ClC6H3}(PBzCyPh)] has been determined by single crystal X-ray analysis. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：1943 / 1955

页数：13

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