Isolation and characterisation of C60(CF3)2

被引：21

作者：

Avent, AG

Boltalina, OV ^{[1
]}

Goryunkov, A

Darwish, AD

Markov, VY

Taylor, R

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Univ Sussex, Chem Lab, CPES Sch, Brighton BN1 9QJ, E Sussex, England

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2002年 / 10卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1081/FST-120014738

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

From the products of reactions of [60]fullerene with either K2PtF6 at 470degreesC or AgF at 520degreesC, we have isolated C-60(CF3)(2), the simplest trifluoromethylfullerene, which gives a single F-19 NMR line at -69.5 ppm. The HPLC retention time is less than that Of C60F2 confirming the trend observed for other fluoro- vs. trifluoromethylfullerenes namely that the latter elute more rapidly. Other trifluoromethyl- containing species, C-60(CF3)(4)O, C60F5CF3, C-60(CF3)(4)H-2, C-60(CF3)(6)H-2, and C-60(CF3H)(3) were detected in the product mixture.

引用

页码：235 / 241

页数：7

共 29 条

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