Controlled synthesis of one-dimensional single-crystal Co3O4 nanowires

被引:19
作者
Du, Jin [1 ,2 ]
Chai, Lanlan [1 ,2 ]
Wang, Gongming [1 ,2 ]
Li, Kai [1 ,2 ]
Qian, Yitai [1 ,2 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Anhua 230026, Peoples R China
[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Anhua 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1071/CH07186
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniform Co3O4 nanowires with diameters of similar to 80 nm and lengths of 10 - 20 mu m have been prepared by a hydrothermal reaction and sequential decomposition of the intermediate product. Transmission electron microscopy characterization and selected-area electron diffraction patterns show that the nanowires elongate along the [ 110] direction. The amount of CO(NH2)(2) employed and the heating rate of calcination have a key effect on the morphology of the product. In addition, analysis of the optical properties indicates a blue shift of the bandgaps and reveals the semiconductive nature of the products.
引用
收藏
页码:153 / 158
页数:6
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