Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination

被引：48

作者：

Hannedouche, Jerome ^{[1
]}

Aillaud, Isabelle ^{[1
]}

Collin, Jacqueline ^{[1
]}

Schulz, Emmanuelle ^{[1
]}

Trifonov, Alexander ^{[2
]}

机构：

[1] Univ Paris Sud 11, Equipe Catalyse Mol, ICMMO, UMR CNRS 8182, F-91405 Orsay, France

[2] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603600, Russia

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 30期

关键词：

D O I：

10.1039/b804745f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl3 or YCl3(THF)(3.5) with ligand (R)-L-1 and n-BuLi is described.

引用

页码：3552 / 3554

页数：3

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