Fluxional processes in organotransition-metal C-60 complexes

被引：21

作者：

Green, MLH

Stephens, AHH

机构：

[1] Inorganic Chemistry Laboratory, Oxford, OX1 3QR, South Parks Road

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 08期

关键词：

D O I：

10.1039/a700385d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Variable-temperature and EXSY C-13 NMR studies on [M(NO)(PPh3)(2)(eta(2)-C-60)] (M = Co, Rh), [Ru(NO)(PPh3)(2)(eta(2)-C-60)H] and [Rh(CO)(PPh3)(2)(eta(2)-C-60)H] show the presence of C-60-metal moiety rotation and migration processes and the data allow extensive assignment of delta(C-60) C-13 NMR resonances.

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页码：793 / 794

页数：2

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