FACILE CLEAVAGE OF CARBON-PALLADIUM BONDS IN C60PDN WITH PHOSPHINES AND PHOSPHITES - AN ALTERNATIVE ROUTE TO (ETA-2-C60)PDL2 AND DISCOVERY OF FLUXIONARITY SUGGESTING THE ROTATION OF C-60 ON THE PDL2 SPECIES IN SOLUTION

被引：48

作者：

NAGASHIMA, H

YAMAGUCHI, H

KATO, Y

SAITO, Y

HAGA, MA

ITOH, KJ

机构：

[1] MIE UNIV, DEPT ELECT & ELECTR ENGN, TSU, MIE 514, JAPAN

[2] MIE UNIV, FAC EDUC, DEPT CHEM, TSU, MIE 514, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 12期

关键词：

D O I：

10.1246/cl.1993.2153

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon-palladium bonds in C60Pdn are easily cleaved with phosphines and phosphites to afford C60[PdL2]n. The reaction with C60Pdn (n = 1.0-1.4) offers an alternative synthetic route to C60PdL2. Fluxional behavior indicating rotation of C60 on the PdL2 species in solution is observed on C-13 NMR spectra of C60PdL2, where L = PMe2Ph, PPh2Me, and P(OMe)3.

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页码：2153 / 2156

页数：4

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