SYNTHESIS AND REACTIONS OF ORGANOPLATINUM COMPOUNDS OF C-60, C60PTN

被引：75

作者：

NAGASHIMA, H

KATO, Y

YAMAGUCHI, H

KIMURA, E

KAWANISHI, T

KATO, M

SAITO, Y

HAGA, M

ITOH, K

机构：

[1] TOYOHASHI UNIV TECHNOL, CHEMOMETR RES CTR, TOYOHASHI, AICHI 441, JAPAN

[2] MIE UNIV, DEPT ELECT & ELECTR ENGN, TSU, MIE 514, JAPAN

[3] MIE UNIV, FAC EDUC, DEPT CHEM, TSU, MIE 514, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 07期

关键词：

D O I：

10.1246/cl.1994.1207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The organoplatinum compound of C-60, C60Ptn (n = 1-2), was prepared either by the reaction of C-60 with Pt(dba)(2) or by the thermal disproportionation of C60Ptn (n = ca. 1). The C60Ptn obtained catalyzed the hydrogenation of diphenylacetylene regardless of the platinum content. Cleavage of carbon-platinum bonds of C60Ptn (n = ca. 1) was accomplished by the reactions with phosphines or phosphites, which provided general access to (eta(2)-C-60)PtL(2)[L = phosphines and phosphites].

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页码：1207 / 1210

页数：4

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