Monitoring a progressing transesterification reaction by fiber-optic near infrared spectroscopy with correlation to 1H nuclear magnetic resonance spectroscopy

被引：255

作者：

Knothe, G ^{[1
]}

机构：

[1] USDA ARS, Natl Ctr Agr Utilizat Res, Peoria, IL 61604 USA

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 2000年 / 77卷 / 05期

关键词：

biodiesel; fiber-optic probe; fuel quality; near infrared spectroscopy; nuclear magnetic resonance; soybean oil; transesterification; vegetable oils;

D O I：

10.1007/s11746-000-0078-5

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Biodiesel is a promising alternative diesel fuel obtained from vegetable oils, animal fats, or waste oils by transesterifying the oil or fat with an alcohol such as methanol. In an extension of previous work, fiber-optic near infrared spectroscopy was used to quantitatively monitor the transesterification reaction (6-L scale) of a vegetable oil (soybean oil) to methyl soyate. The results were correlated with H-1 nuclear magnetic resonance spectroscopy. The method described here can be applied to the transesterification of other vegetable oils.

引用

页码：489 / 493

页数：5

共 40 条

[31] FT-NIR SPECTROSCOPY OF SOME LONG-CHAIN FATTY-ACIDS AND ALCOHOLS [J].

OZAKI, Y ;

LIU, YL ;

CZARNECKI, MA ;

NODA, I .

MACROMOLECULAR SYMPOSIA, 1995, 94 :51-59

[32] MINOR COMPONENTS IN VEGETABLE OIL METHYL-ESTERS .1. STEROLS IN RAPE SEED OIL METHYL-ESTER [J].

PLANK, C ;

LORBEER, E .

FETT WISSENSCHAFT TECHNOLOGIE-FAT SCIENCE TECHNOLOGY, 1994, 96 (10) :379-386

[33] ONLINE LIQUID-CHROMATOGRAPHY GAS-CHROMATOGRAPHY FOR THE ANALYSIS OF FREE AND ESTERIFIED STEROLS IN VEGETABLE OIL METHYL-ESTERS USED AS DIESEL FUEL SUBSTITUTES [J].

PLANK, C ;

LORBEER, E .

JOURNAL OF CHROMATOGRAPHY A, 1994, 683 (01) :95-104

[34] SIMULTANEOUS DETERMINATION OF GLYCEROL, AND MONODIGLYCERIDES, DIGLYCERIDES AND TRIGLYCERIDES IN VEGETABLE OIL METHYL-ESTERS BY CAPILLARY GAS-CHROMATOGRAPHY [J].

PLANK, C ;

LORBEER, E .

JOURNAL OF CHROMATOGRAPHY A, 1995, 697 (1-2) :461-468

[35] Potential biodiesel markets and their economic effects on the agricultural sector of the United States [J].

Raneses, AR ;

Glaser, LK ;

Price, JM ;

Duffield, JA .

INDUSTRIAL CROPS AND PRODUCTS, 1999, 9 (02) :151-162

[36]

SADEGHIJORABCHI H, 1994, SPECTROSC EUR, V6, P20

[37]

SADEGHIJORABCHI H, 1994, SPECTROSC EUR, V6, P18

[38]

SADEGHIJORABCHI H, 1994, SPECTROSC EUR, V6, P16

[39]

Sato T., 1997, Lipid Technology, V9, P46

[40] ANALYSIS OF TRIGLYCERIDE METHANOLYSIS MIXTURES USING ISOCRATIC HPLC WITH DENSITY DETECTION [J].

TRATHNIGG, B ;

MITTELBACH, M .

JOURNAL OF LIQUID CHROMATOGRAPHY, 1990, 13 (01) :95-105

← 1 2 3 4 →