N-Heterocyclic Carbene Stabilized Digermanium(0)

被引：272

作者：

Sidiropoulos, Anastas ^{[1
]}

Jones, Cameron ^{[1
]}

Stasch, Andreas ^{[1
]}

Klein, Susanne ^{[2
]}

Frenking, Gernot ^{[2
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 51期

基金：

澳大利亚研究理事会;

关键词：

carbene ligands; density functional calculations; germanium; magnesium; metal-metal interactions; TRANSITION-STATE METHOD; COORDINATION CHEMISTRY; DOUBLE-BOND; COMPLEXES; P-4; CARBODICARBENE; COMPOUND; ANALOGS; ADDUCT; BENT;

D O I：

10.1002/anie.200905495

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zero Ge! Reductions of an N-heterocyclic carbene (NHC) adduct of GeCl2 with magnesium(1) dimers afford a dimeric compound (see picture), which structural and theoretical studies show to contain a singlet digermanium(0) fragment DGe=GeD datively coordinated by two NHC ligands. © 2009 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：9701 / 9704

页数：4

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