Isolation of a tetrameric cation-cation complex of pentavalent uranyl

被引：93

作者：

Burdet, Fabien ^{[1
]}

Pecaut, Jacques ^{[1
]}

Mazzanti, Marinella ^{[1
]}

机构：

[1] CEA, SCIB, Dept Rech Fondamentale Mat Condensee, UMRE 3,UJF,Lab Reconaissance Ion & Chim Coordinat, F-38054 Grenoble 09, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 51期

关键词：

D O I：

10.1021/ja067445t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polymetallic assembly containing mutually coordinated highly reactive UO2+ groups was isolated in the presence of dibenzoylmethanate. NMR studies showed unambiguously the presence of the cation-cation complex in pyridine solution while more polar solvents lead to the disruption of the O2+/UO2+ interaction and increased stability. Copyright © 2006 American Chemical Society.

引用

页码：16512 / 16513

页数：2

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