Asymmetric epoxidation of electron-deficient olefins

被引:318
作者
Porter, MJ
Skidmore, J
机构
[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England
[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
关键词
D O I
10.1039/b001780i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In recent years, methods for the asymmetric epoxidation of electron-deficient olefins, particularly alpha,beta-enones, have attracted widespread attention. A critical review is presented of these methods, which include epoxidations with chiral metal hydroperoxides, asymmetric phase-transfer methods, the use of polyamino acid catalysts and the use of chiral dioxiranes.
引用
收藏
页码:1215 / 1225
页数:11
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