Asymmetric epoxidation of electron-deficient olefins

被引：318

作者：

Porter, MJ

Skidmore, J

机构：

[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b001780i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In recent years, methods for the asymmetric epoxidation of electron-deficient olefins, particularly alpha,beta-enones, have attracted widespread attention. A critical review is presented of these methods, which include epoxidations with chiral metal hydroperoxides, asymmetric phase-transfer methods, the use of polyamino acid catalysts and the use of chiral dioxiranes.

引用

页码：1215 / 1225

页数：11

共 89 条

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