Spectroscopic evaluation of molecular imprinting polymerization systems

被引：101

作者：

Andersson, HS ^{[1
]}

Nicholls, IA ^{[1
]}

机构：

[1] UNIV KALMAR,DEPT NAT SCI,BIOORGAN CHEM LAB,S-39129 KALMAR,SWEDEN

来源：

BIOORGANIC CHEMISTRY | 1997年 / 25卷 / 03期

关键词：

molecular imprinting; molecular recognition; UV spectroscopy; synthetic receptor;

D O I：

10.1006/bioo.1997.1067

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

An evaluation of the extent of self-assembly of functional monomer-template complexes in molecularly imprinted polymer prepolymerization mixtures has been performed. The results provide general insights into the nature of the prepolymerization self-assembly phase. Furthermore, the method allows for the estimation of the number of medium-to high-affinity recognition sites in the product polymer and a means for the rapid evaluation of molecular imprinting systems. (C) 1997 Academic Press.

引用

页码：203 / 211

页数：9

共 25 条

[1]

Andersson HS, 1996, J MOL RECOGNIT, V9, P675, DOI 10.1002/(SICI)1099-1352(199634/12)9:5/6<675::AID-JMR320>3.0.CO

[2]

2-C

[3]

ANDERSSON HS, 1997, IN PRESS RECENT RES

[4] Recognition in molecularly imprinted polymer alpha(2)-adrenoreceptor mimics [J].

Berglund, J ;

Nicholls, IA ;

Lindbladh, C ;

Mosbach, K .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1996, 6 (18) :2237-2242

[5] THE DESIGN OF MOLECULAR HOSTS, GUESTS, AND THEIR COMPLEXES (NOBEL LECTURE) [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (08) :1009-1020

[6] TEMPLATE-MEDIATED SYNTHESIS OF METAL-COMPLEXING POLYMERS FOR MOLECULAR RECOGNITION [J].

DHAL, PK ;

ARNOLD, FH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (19) :7417-7418

[7] MOLECULAR IMPRINTS MAKE A MARK [J].

FLAM, F .

SCIENCE, 1994, 263 (5151) :1221-1222

[8] SUPRAMOLECULAR CHEMISTRY - SCOPE AND PERSPECTIVES MOLECULES, SUPERMOLECULES, AND MOLECULAR DEVICES [J].

LEHN, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (01) :89-112

[9] Highly stereoselective molecularly imprinted polymer synthetic receptors for cinchona alkaloids [J].

Matsui, J ;

Nicholls, IA ;

Takeuchi, T .

TETRAHEDRON-ASYMMETRY, 1996, 7 (05) :1357-1361

[10] The emerging technique of molecular imprinting and its future impact on biotechnology [J].

Mosbach, K ;

Ramstrom, O .

BIO-TECHNOLOGY, 1996, 14 (02) :163-170

← 1 2 3 →