Improved electric properties in BiFeO3 films by the doping of Ti

被引:81
作者
Liu, Hongri
Liu, Zuli [1 ]
Yao, Kailun
机构
[1] Huazhong Univ Sci & Technol, Dept Phys, Wuhan 430074, Peoples R China
[2] Hubei Normal Univ, Dept Phys, Huangshi 435002, Peoples R China
基金
中国国家自然科学基金;
关键词
sol gel; magnetism; ferroelectricity; leakage conduction; dielectric constant; CHEMICAL SOLUTION DEPOSITION; THIN-FILMS; MAGNETIC-PROPERTIES;
D O I
10.1007/s10971-006-0514-x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We prepared BiFe1-x Ti (x) O3+delta (BFTO) films by sol gel process and various oriented films were deposited on LaNiO3 coated SiO2/Si substrates with different x. The effects of Ti substitution on dielectric, ferroelectric, magnetic and leakage conduction properties in BFTO system have been studied. Enhanced ferroelectricity was observed at room temperature due to the substitution of Ti. The largest double remnant polarization of 3.8 mu C/cm(2) was acquired in the film with x = 0.10. Further more, it was observed that the dielectric constants were also enhanced by the substitution of Ti. The film with x = 0.10 has the largest dielectric constant below 100 kHz and Debye-like relaxation were observed in the films with x = 0.05 and 0.10. The leakage conduction was reduced with the increasing of the content of Ti. More over, the magnetism was also altered by the substitution.
引用
收藏
页码:123 / 128
页数:6
相关论文
共 20 条
[1]   Preparation of conductive LaNiO3 film electrodes by a simple chemical solution deposition technique for integrated ferroelectric thin film devices [J].
Bao, DH ;
Yao, X ;
Wakiya, N ;
Shinozaki, K ;
Mizutani, N .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (10) :1217-1221
[2]   Structural, dielectric and pyroelectric studies of Pb1-xCaxTiO3 thin films [J].
Chopra, S ;
Sharma, S ;
Goel, TC ;
Mendiratta, RG .
SOLID STATE COMMUNICATIONS, 2003, 127 (04) :299-304
[3]   Evidence for the likely occurrence of magnetoferroelectricity in the simple perovskite, BiMnO3 [J].
dos Santos, AM ;
Parashar, S ;
Raju, AR ;
Zhao, YS ;
Cheetham, AK ;
Rao, CNR .
SOLID STATE COMMUNICATIONS, 2002, 122 (1-2) :49-52
[4]   Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite [J].
Ederer, C ;
Spaldin, NA .
PHYSICAL REVIEW B, 2005, 71 (06)
[5]   MAGNETIC-PROPERTIES OF BIFEO3-BATIO3 AND BIFEO3-PBTI(ZR)O3 GLASSY SPUTTERED FILMS [J].
FUJII, T ;
JINZENJI, S ;
ASAHARA, Y ;
KAJIMA, A ;
SHINJO, T .
JOURNAL OF APPLIED PHYSICS, 1988, 64 (10) :5434-5436
[6]   Multiferroic BiFeO3 thin films processed via chemical solution deposition:: Structural and electrical characterization -: art. no. 094901 [J].
Iakovlev, S ;
Solterbeck, CH ;
Kuhnke, M ;
Es-Souni, M .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (09)
[7]   STRUCTURE OF A FERROELECTRIC AND FERROELASTIC MONODOMAIN CRYSTAL OF THE PEROVSKITE BIFEO3 [J].
KUBEL, F ;
SCHMID, H .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1990, 46 :698-702
[8]   Preparation and characterization of BiFeO3 thin films grown on LaNiO3-coated SrTiO3 substrate by chemical solution deposition [J].
Li, YW ;
Sun, JL ;
Chen, J ;
Meng, XJ ;
Chu, JH .
JOURNAL OF CRYSTAL GROWTH, 2005, 285 (04) :595-599
[9]   Electric and magnetic properties of multiferroic (BiFeO3)1-x-(PbTiO3)x films prepared by the sol-gel process [J].
Liu, HR ;
Liu, ZL ;
Liu, Q ;
Yao, KL .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2006, 39 (06) :1022-1027
[10]   Ferroelectric properties of BiFeO3 films grown by sol-gel process [J].
Liu, HR ;
Liu, ZL ;
Liu, Q ;
Yao, KL .
THIN SOLID FILMS, 2006, 500 (1-2) :105-109