Synthesis, structure and magnetic properties of a novel 1D coordination polymer {[Cu2(amtrz)4(1,1-μ-NCS)2](ClO4)2•H2O}n

被引：44

作者：

Ding, Bin

Huang, Yong Quan

Liu, Yuan Yuan

Shi, Wei

Cheng, Peng ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 01期

基金：

中国国家自然科学基金;

关键词：

crystal structure; copper(II) complex; antiferromagnetic interaction;

D O I：

10.1016/j.inoche.2006.08.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel one-dimensional (1D) coordination polymer {[Cu-2(amtrz)(4)(1,1-mu-NCS)(2)](ClO4)(2)center dot H2O}(n) (1) (amtrz = 4-amino-1,2,4-triazole) was synthesized and structurally characterized. The 1D chains of 1 are linked via short intermolecular (SS)-S-... interactions to form a 3D supramolecular architecture with 1D channels along c direction, while water molecules and perchlorate anions were encapsulated in the channels. Variable-temperature magnetic susceptibilities (2-300 K) shows antiferromagnetic interactions with J = -51 cm(-1). (c) 2006 Elsevier B.V. All rights reserved.

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页码：7 / 10

页数：4

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