Characterization of the broad green band luminescence in CVD and synthetic Ib diamond

被引:19
作者
Iakoubovskii, K [1 ]
Adriaenssens, GJ [1 ]
机构
[1] Katholieke Univ Leuven, Semicond Phys Lab, B-3001 Heverlee, Belgium
关键词
CVD; defect; photoluminescence; sp(2) bonding;
D O I
10.1016/S0925-9635(99)00275-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Results of photoluminescence (PL) and PL excitation (PLE) measurements on the broad green band in CVD and synthetic Ib diamond are reported. PLE spectra show that the green band in CVD diamond films is composed of two components. The first component correlates with the a-C content and is attributed to recombination in amorphous carbon. The second component increases with surface hydrogenation in CVD films, but remains almost unchanged in Ib diamond. On the basis of excitation and temperature dependencies of PL, the second band is ascribed to the donor-acceptor pair recombination. The photoionization threshold for the transition from the valence band to the donor is found to be 3.25 eV. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:1017 / 1020
页数:4
相关论文
共 22 条
[1]   THE ORIGIN OF THE BROAD-BAND LUMINESCENCE AND THE EFFECT OF NITROGEN DOPING ON THE OPTICAL-PROPERTIES OF DIAMOND FILMS [J].
BERGMAN, L ;
MCCLURE, MT ;
GLASS, JT ;
NEMANICH, RJ .
JOURNAL OF APPLIED PHYSICS, 1994, 76 (05) :3020-3027
[2]   MICROPHOTOLUMINESCENCE AND RAMAN-SCATTERING STUDY OF DEFECT FORMATION IN DIAMOND FILMS [J].
BERGMAN, L ;
STONER, BR ;
TURNER, KF ;
GLASS, JT ;
NEMANICH, RJ .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (08) :3951-3957
[3]   THE CHARACTERIZATION OF POINT-DEFECTS IN DIAMOND BY LUMINESCENCE SPECTROSCOPY [J].
COLLINS, AT .
DIAMOND AND RELATED MATERIALS, 1992, 1 (5-6) :457-469
[4]   OPTICAL STUDIES OF VIBRONIC BANDS IN YELLOW LUMINESCING NATURAL DIAMONDS [J].
COLLINS, AT ;
MOHAMMED, K .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1982, 15 (01) :147-158
[5]  
DEAN PJ, 1965, PHYS REV A, V139, P588
[6]   IMAGING OF BORON DOPANT IN HIGHLY ORIENTED DIAMOND FILMS BY CATHODOLUMINESCENCE IN A TRANSMISSION ELECTRON-MICROSCOPE [J].
GRAHAM, RJ ;
SHAAPUR, F ;
KATO, Y ;
STONER, BR .
APPLIED PHYSICS LETTERS, 1994, 65 (03) :292-294
[7]   Investigation of the effect of hydrogen on electrical and optical properties in chemical vapor deposited on homoepitaxial diamond films [J].
Hayashi, K ;
Yamanaka, S ;
Watanabe, H ;
Sekiguchi, T ;
Okushi, H ;
Kajimura, K .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (02) :744-753
[8]   Hydrogen-related gap states in the near surface of chemical vapor deposited homoepitaxial diamond films [J].
Hayashi, K ;
Watanabe, H ;
Yamanaka, S ;
Sekiguchi, T ;
Okushi, H ;
Kajimura, K .
DIAMOND AND RELATED MATERIALS, 1997, 6 (2-4) :303-307
[9]   Formation and relaxation of hydrogen-related defects in the subsurface region of diamond films [J].
Hayashi, K ;
Sekiguchi, T ;
Okushi, H .
DEFECTS IN SEMICONDUCTORS - ICDS-19, PTS 1-3, 1997, 258-2 :745-750
[10]  
Horikoshi K, 1997, EXTREMOPHILES, V1, P1