Cavity effect amplification in the recognition of dicarboxylic acids by initial ditopic H-bond formation followed by kinetic trapping

被引：25

作者：

Brotherhood, Peter R. ^{[1
]}

Wu, Richard A. -S. ^{[1
]}

Turner, Peter ^{[1
]}

Crossley, Maxwell J. ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 03期

关键词：

D O I：

10.1039/b614575b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Di[dihydroxotin( IV)] Troger's base bis-porphyrin 1, a host molecule with two internal and two external guest interaction sites, binds <= 1 equivalent of dicarboxylic acid quantitatively within the chiral cavity, a regioselectivity amplified by initial ditopic H-bond formation, followed by kinetic trapping.

引用

页码：225 / 227

页数：3

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