The authors report transport property measurements of individual GaN nanowire field effect transistors and the correlation of the electron mobilities with the existence of grain boundaries in these nanowires. Room temperature field effect electron mobilities as high as 319 cm(2) V-1 s(-1) were obtained for the 200 nm diameter nanowires. Mobilities calculated from these reliable nanowire field effect transistors indicated that the surface scattering plays a dominant role in smaller diameter nanowires, whereas for intermediate diameter devices transport is dominated by grain boundary scattering. Reduction of the mobility with decreasing diameter of nanowires can be explained using "continuous surface" model. (c) 2007 American Institute of Physics.