Novel zigzag 1D coordination polymer from copper(II) chloride and N,N′-{2,4-di[(di-pyridin-2-yl)amine]-1,3,5-triazine} ethylenediamine exhibiting ferromagnetic interactions

被引：24

作者：

de Hoog, P

Gamez, P

Roubeau, O

Lutz, M

Driessen, WL

Spek, AL

Reedijk, J

机构：

[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 01期

关键词：

D O I：

10.1039/b206344a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) chloride reacts with the polydentate 1,3,5-triazine containing ligand opytrizediam in methanol-THF to form a unique infinite zigzag coordination polymer in which trinuclear copper complexes are bridged by chloride anions, giving rise to five-coordinated ferromagnetically coupled copper pseudodimers.

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页码：18 / 21

页数：4

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