Ball-, bowl-, and belt-shaped conjugated systems and their complexing abilities:: Exploration of the concave-convex π-π interaction

被引:515
作者
Kawase, Takeshi [1 ]
Kurata, Hiroyuki [1 ]
机构
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
关键词
D O I
10.1021/cr0509657
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An overview is given of the supramolecular properties of the curved conjugated systems possessing a ball-shaped, bowl-shaped, or belt-shaped structure to explore the nature of the concave-convex π-π interaction. Under ball-shaped systems, emphasis is on complexes with small molecules, complexes with traditional hosts and designed host molecules. For ball-shaped systems, discussion covers stacking structure and host properties. With regards to belt-shaped systems, focus is on cyclacene and related compounds, open-cage fullerenes, cyclocarbon, cyclo-para-phenylene and the hybrid compounds and carbon nanorings. The complexing abilities of carbon nanorings are also discussed.
引用
收藏
页码:5250 / 5273
页数:24
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