Facile Preparation of 3,4-Diarylpyrroles and Hydrogen by a Platinum(II) Terpyridyl Complex

被引：17

作者：

Wang, Deng-Hui

Peng, Ming-Li

Han, Yong

Chen, Bin

Jung, Chen-Ho

Wu, Li-Zhu ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 21期

基金：

中国国家自然科学基金;

关键词：

EXCITED-STATE; CHEMISTRY; PYRROLES; WATER;

D O I：

10.1021/ic901666j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

With visible-light irradiation of the platinum(II) terpyridyl complex 1 (lambda > 450 nm), an effective photocatalytic conversion from readily available 3,4-diaryl-2,5-dihydropyrroles (2a-2e) to 3,4-diarylpyrroles (3a-3e) and hydrogen (H-2) is achieved with high efficiency and large catalytic turnover in a homogeneous solution.

引用

页码：9995 / 9997

页数：3

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