Recent progress in asymmetric heterogeneous catalysis: use of polymer-supported catalysts

被引：58

作者：

Saluzzo, C ^{[1
]}

ter Halle, R ^{[1
]}

Touchard, F ^{[1
]}

Fache, F ^{[1
]}

Schulz, E ^{[1
]}

Lemaire, M ^{[1
]}

机构：

[1] CPE, UCBL, UMR 5622, Lab Catalyse & Synthese Organ, F-69622 Villeurbanne, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 603卷 / 01期

关键词：

heterogeneous catalysis; asymmetric catalysis; polymers;

D O I：

10.1016/S0022-328X(00)00050-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric heterogeneous catalytic reduction of carbonyl bonds by hydrogen transfer reduction or hydrogenation by means of molecular hydrogen as well as the asymmetric allylic substitution of allylic acetates are reported. In order to perform these reactions, new polymer-supported catalysts were employed. These polymers are either a Merrifield resin with a chiral pendent ligand or a chiral main chain polymer with ureas, thioureas and a diphosphine as functional groups. Comparison of the results obtained in these heterogeneous asymmetric reactions was made with those obtained in the homogeneous ones. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：30 / 39

页数：10

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