Spectroelectrochemistry: the best of two worlds

被引：335

作者：

Kaim, Wolfgang ^{[1
]}

Fiedler, Jan ^{[2
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany

[2] Acad Sci Czech Republic, J Heyrovsky Inst Phys Chem, Vvi, CZ-18223 Prague, Czech Republic

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 12期

关键词：

DIFFERENT OXIDATION-STATES; MIXED-VALENT COMPLEXES; ELECTRONIC-STRUCTURE; POLYNUCLEAR COMPLEXES; DELTA-E-1/2; VALUES; REACTION CENTERS; CHELATE LIGANDS; CHARGE-TRANSFER; IR; SPECTROSCOPY;

D O I：

10.1039/b504286k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of reaction-oriented electrochemistry with species-focussed spectroscopy in spectroelectrochemistry (SEC) allows for a more complete analysis of single and multiple electron-transfer processes and redox reactions in general. Practical considerations and guidelines are provided in this tutorial review, and selected examples involving UV-VIS-NIR and IR absorption spectroscopy as well as electron paramagnetic resonance (EPR) are presented to illustrate the potential and the applicability of this technique.

引用

页码：3373 / 3382

页数：10

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