Metal-mediated diboration of Alkynes with [2]borametalloarenophanes under stoichiometric, homogeneous, and heterogeneous conditions

被引：93

作者：

Braunschweig, Holger ^{[1
]}

Kupfer, Thomas ^{[1
]}

Lutz, Matthias ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Seeler, Fabian ^{[1
]}

Sigritz, Rainer ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 47期

关键词：

boron; diboration; heterogeneous catalysis; palladium; platinum;

D O I：

10.1002/anie.200603130

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) ansa-[2]Borabis(benzene)chromophane and ansa-[2]boraferroarenophane were treated with alkynes in the presence of catalytic amounts of platinum or palladium/charcoal (see example) to afford the corresponding ansa-bis(boryl)alkenes in excellent yields and without detectable side products. The use of Pt and Pd are the first examples of diboration reactions of alkynes to be conducted under heterogeneous conditions. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8048 / 8051

页数：4

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