Direct Electrochemical Reduction of Single-Layer Graphene Oxide and Subsequent Functionalization with Glucose Oxidase

被引:596
作者
Wang, Zhijuan [1 ]
Zhou, Xiaozhu [1 ]
Zhang, Juan [1 ]
Boey, Freddy [1 ]
Zhang, Hua [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
关键词
CARBON NANOTUBES;
D O I
10.1021/jp906348x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A direct electrochemical method to reduce single-layer graphene oxide (GO) adsorbed on the 3-aminopropyltriethoxysilane (APTES)-modified conductive electrodes is proposed. The reduced GO adsorbed on glassy carbon electrode was modified with glucose oxidase (GOx) by covalent bonding via a polymer generated by electrografting N-succinimidyl acrylate (NSA). The direct electron transfer between the electrode and GOx molecules was realized. The bioactivity of GOx maintains very well on the electrode. The thus-prepared GOx-modified electrode was successfully used to detect glucose.
引用
收藏
页码:14071 / 14075
页数:5
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