Efficient synthesis of chiral acetylene dithioethers in enantiomerically pure form

被引：11

作者：

Balsells, J ^{[1
]}

Moyano, A ^{[1
]}

Pericas, MA ^{[1
]}

Riera, A ^{[1
]}

机构：

[1] UNIV BARCELONA,UNITAT RECERCA SINTESI ASIMETR,DEPT QUIM ORGAN,E-08028 BARCELONA,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 10期

关键词：

D O I：

10.1016/S0957-4166(97)00126-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral acetylene dithioethers have been synthesized by the first time in enantiomerically pure form through a high yield (93-100%), one-pot procedure involving the successive treatment of trichloroethylene with three equivalents of lithium bis(trimethylsilyl)amide and two equivalents of a chiral thiol in diethyl ether solution. (C) 1997 Elsevier Science Ltd.

引用

页码：1575 / 1580

页数：6

共 19 条

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