Strategies to immobilize well-defined olefin metathesis catalysts: Supported homogeneous catalysis vs. surface organometallic chemistry

被引:193
作者
Coperet, C. [1 ]
Basset, J. -M. [1 ]
机构
[1] ESCPE Lyon, CNRS, UMR 9986, Lab Chim Oraganomet Surface, F-69616 Villeurbanne, France
关键词
heterogeneous catalysts; immobilization; olefin metathesis; supported homogeneous catalysts; surface organometallic chemistry;
D O I
10.1002/adsc.200600443
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This review is mainly devoted to a description of the strategies that have been implemented to develop well-defined olefin metathesis catalysts immobilized on solid supports. Two main approaches have been investigated involving supported homogenous catalysts or heterogeneous catalysts prepared by surface organometallic chemistry. Advantages, limitations and possible developments of these systems are discussed.
引用
收藏
页码:78 / 92
页数:15
相关论文
共 147 条
[81]   Synthesis, structure, and activity of enhanced initiators for olefin metathesis [J].
Love, JA ;
Sanford, MS ;
Day, MW ;
Grubbs, RH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (33) :10103-10109
[82]   Monolithic systems: From separation science to heterogeneous catalysis [J].
Lubbad, S ;
Mayr, B ;
Mayr, M ;
Buchmeiser, MR .
MACROMOLECULAR SYMPOSIA, 2004, 210 :1-9
[83]   ON THE NATURE OF METHYLTRIOXORHENIUM(VII) ENCAPSULATED IN ZEOLITE-Y [J].
MALEK, A ;
OZIN, G .
ADVANCED MATERIALS, 1995, 7 (02) :160-163
[84]   Monolithic disk-supported metathesis catalysts for use in combinatorial chemistry [J].
Mayr, M ;
Wang, DR ;
Kröll, R ;
Schuler, N ;
Prühs, S ;
Fürstner, A ;
Buchmeiser, MR .
ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (2-3) :484-492
[85]  
Mayr M, 2002, ADV SYNTH CATAL, V344, P712, DOI 10.1002/1615-4169(200208)344:6/7<712::AID-ADSC712>3.0.CO
[86]  
2-W
[87]  
Mayr M, 2001, ANGEW CHEM INT EDIT, V40, P3839, DOI 10.1002/1521-3773(20011015)40:20<3839::AID-ANIE3839>3.0.CO
[88]  
2-O
[89]   ROMP and RCM catalysed by (R3P)2Cl2Ru=CHPh immobilised on a mesoporous support [J].
Melis, K ;
De Vos, D ;
Jacobs, P ;
Verpoort, F .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 169 (1-2) :47-56
[90]   Ring-closure metathesis in supercritical carbon dioxide as sole solvent with use of covalently immobilized ruthenium catalysts [J].
Michalek, F ;
Mädge, D ;
Rühe, J ;
Bannwarth, W .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (03) :577-581