学术探索
学术期刊
新闻热点
数据分析
智能评审

Strategies to immobilize well-defined olefin metathesis catalysts: Supported homogeneous catalysis vs. surface organometallic chemistry

被引：193
作者：
Coperet, C. [1 ]
Basset, J. -M. [1 ]
机构：
[1] ESCPE Lyon, CNRS, UMR 9986, Lab Chim Oraganomet Surface, F-69616 Villeurbanne, France
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 1-2期
关键词：
heterogeneous catalysts; immobilization; olefin metathesis; supported homogeneous catalysts; surface organometallic chemistry;
D O I：
10.1002/adsc.200600443
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
This review is mainly devoted to a description of the strategies that have been implemented to develop well-defined olefin metathesis catalysts immobilized on solid supports. Two main approaches have been investigated involving supported homogenous catalysts or heterogeneous catalysts prepared by surface organometallic chemistry. Advantages, limitations and possible developments of these systems are discussed.
引用
收藏
页码：78 / 92
页数：15
相关论文
共 147 条
[111]   Molybdenum and tungsten imido alkylidene complexes as efficient olefin-metathesis catalysts [J].
Schrock, RR ;
Hoveyda, AH .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (38) :4592-4633
[112]   LIVING RING-OPENING METATHESIS POLYMERIZATION CATALYZED BY WELL-CHARACTERIZED TRANSITION-METAL ALKYLIDENE COMPLEXES [J].
SCHROCK, RR .
ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (05) :158-165
[113]   Recent advances in olefin metathesis by molybdenum and tungsten imido alkylidene complexes [J].
Schrock, RR .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 213 (01) :21-30
[114]   ALKYLIDENE COMPLEXES OF NIOBIUM AND TANTALUM [J].
SCHROCK, RR .
ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (03) :98-104
[115]  
Schürer SC, 2000, ANGEW CHEM INT EDIT, V39, P3898, DOI 10.1002/1521-3773(20001103)39:21<3898::AID-ANIE3898>3.0.CO
[116]  
2-X
[117]   Reactions of M(N-2,6-i-Pr2C6H3)(CHR)(CH2R′)2 (M = Mo, W) complexes with alcohols to give olefin metathesis catalysts of the type M(N-2,6-i-Pr2C6H3)(CHR)(CH2R′)(OR") [J].
Sinha, A ;
Lopez, LPH ;
Schrock, RR ;
Hock, AS ;
Müller, P .
ORGANOMETALLICS, 2006, 25 (06) :1412-1423
[118]   Reactions of Mo(NAr)(CH-t-Bu)(CH2-t-Bu)2 with alcohols to give metathesis catalysts of the type Mo(NAr)(CH-t-Bu)(CH2-t-Bu)(OR) [J].
Sinha, A ;
Schrock, RR .
ORGANOMETALLICS, 2004, 23 (08) :1643-1645
[119]  
Sinner FM, 2000, ANGEW CHEM INT EDIT, V39, P1433, DOI 10.1002/(SICI)1521-3773(20000417)39:8<1433::AID-ANIE1433>3.0.CO
[120]  
2-B
6789101112131415