Generation of aryl radicals from arylboronic acids by manganese(III) acetate:: Synthesis of biaryls and heterobiaryls

被引：120

作者：

Demir, AS ^{[1
]}

Reis, Ö ^{[1
]}

Emrullahoglu, M ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 02期

关键词：

D O I：

10.1021/jo026466c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The efficient generation of aryl radicals from arylboronic acids by manganese(III) acetate is described. In aromatic solvents, in situ generated aryl radicals afford the corresponding biaryls in very good yields. This method works selectively, and yields are better than those from similar, previously described methods. Arylboronic acids carrying sensitive functional groups also work efficiently.

引用

页码：578 / 580

页数：3

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