Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species

被引：91

作者：

Chun, Jiseul ^{[1
,2
]}

Lee, Han Sol ^{[1
,2
]}

Jung, Il Gu ^{[1
,2
]}

Lee, Soon Won ^{[1
,2
]}

Kim, Hae Jin ^{[3
]}

Son, Seung Uk ^{[1
,2
]}

机构：

[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

[2] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea

[3] Korea Basic Sci Inst, Taejon 350333, South Korea

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 07期

基金：

新加坡国家研究基金会;

关键词：

METAL-ORGANIC FRAMEWORK; HYDROGEN STORAGE; ADSORPTION; REDUCTION; CATALYST; LIGANDS; NETWORK; SITES;

D O I：

10.1021/om900768w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new, and direct synthetic route for N-heterocyclic carbene (NHC)-copper complexes was disclosed by heating imidazolium halides with Cu2O. The related synthetic procedure was quite simple and the product easily separable from the reaction mixture by simple filtration. Ultimately, this reaction was successfully applied to decorate three-dimensional (3D)-metal organic frameworks (MOFs) with coordinatively unsaturated NHC-copper species.

引用

页码：1518 / 1521

页数：4

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