Synthesis of new donor-acceptor systems through the association of a tetrathiafulvalene core and fullerene units

被引：14

作者：

Ravaine, S

Delhaes, P

Leriche, P

Salle, M

机构：

[1] CNRS,CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE

[2] UNIV ANGERS,CNRS,IMMO,EP66,F-49045 ANGERS,FRANCE

来源：

SYNTHETIC METALS | 1997年 / 87卷 / 01期

关键词：

fullerene; tetrathiafulvalene;

D O I：

10.1016/S0379-6779(97)80103-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The preparation of three molecular assemblies in which a tetrathiafulvalene (TTF) derivative is covalently linked to one, two or four C-60 molecules is reported. The cyclic voltammograms (CVs) of the supramolecules are the virtual superposition of those of their donor and acceptor parts. In addition, UV-Vis spectra are highly similar to those of the TTF precursors, indicating that no spontaneous electronic transfer occurs between the fullerene spheres and the TTF core.

引用

收藏

页码：93 / 95

页数：3

相关论文

共 17 条

[1] CESIUM TETRATHIAFULVALENE-THIOLATES - KEY SYNTHETIC INTERMEDIATES [J].

BECHER, J ;

LAU, J ;

LERICHE, P ;

MORK, P ;

SVENSTRUP, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (23) :2715-2716

[2] A COPPER(I)-COMPLEXED ROTAXANE WITH 2 FULLERENE STOPPERS [J].

DIEDERICH, F ;

DIETRICHBUCHECKER, C ;

NIERENGARTEN, JF ;

SAUVAGE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (07) :781-782

[3] PREPARATION AND CHARACTERIZATION OF FULLEROID AND METHANOFULLERENE DERIVATIVES [J].

HUMMELEN, JC ;

KNIGHT, BW ;

LEPEQ, F ;

WUDL, F ;

YAO, J ;

WILKINS, CL .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) :532-538

[4] SYNTHESIS OF A RIGID BALL-AND-CHAIN DONOR-ACCEPTOR SYSTEM THROUGH DIELS-ALDER FUNCTIONALIZATION OF BUCKMINSTERFULLERENE (C(60)) [J].

KHAN, SI ;

OLIVER, AM ;

PADDONROW, MN ;

RUBIN, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) :4919-4920

[5] A GREEN FULLERENE - SYNTHESIS AND ELECTROCHEMISTRY OF A DIELS-ALDER ADDUCT OF [60]FULLERENE WITH A PHTHALOCYANINE [J].

LINSSEN, TG ;

DURR, K ;

HANACK, M ;

HIRSCH, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (01) :103-104

[6] SYNTHESIS OF A [60]FULLERENE DERIVATIVE COVALENTLY-LINKED TO A RUTHENIUM(II) TRIS(BIPYRIDINE) COMPLEX [J].

MAGGINI, M ;

DONO, A ;

SCORRANO, G ;

PRATO, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) :845-846

[7] Semiconducting charge transfer complexes from [60]fullerene-tetrathiafulvalene (C-60-TTF) systems [J].

Martin, N ;

Sanchez, L ;

Seoane, C ;

Andreu, R ;

Garin, J ;

Orduna, J .

TETRAHEDRON LETTERS, 1996, 37 (33) :5979-5982

[8]

MEERHOLZ K, 1993, SYNTHETIC MET, V55, P3098

[9] Synthesis and applications of fulleropyrrolidines [J].

Prato, M ;

Maggini, M ;

Scorrano, G .

SYNTHETIC METALS, 1996, 77 (1-3) :89-91

[10] SYNTHESIS, PHYSICAL CHARACTERIZATIONS, AND LANGMUIR FILMS OF NEW METHANOFULLERENES [J].

RAVAINE, S ;

LEPECQ, F ;

MINGOTAUD, C ;

DELHAES, P ;

HUMMELEN, JC ;

WUDL, F ;

PATTERSON, LK .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (23) :9551-9557