Ionic liquids in surface electrochemistry

被引：320

作者：

Liu, Hongtao ^{[2
]}

Liu, Yang ^{[1
]}

Li, Jinghong ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China

[2] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 08期

基金：

中国国家自然科学基金;

关键词：

ELECTRICAL DOUBLE-LAYER; TEMPERATURE MOLTEN-SALTS; CARBON-PASTE; ALUMINUM-CHLORIDE; CYCLIC CARBONATES; ELECTROCATALYTIC BEHAVIOR; DIFFERENTIAL CAPACITANCE; AMPEROMETRIC BIOSENSOR; REVERSIBLE DEPOSITION; PHYSICAL-PROPERTIES;

D O I：

10.1039/b921469k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ionic liquids (IL) are widely used in electrochemistry due to their excellent properties such as good ionic conductivity, wide electrochemical potential window, high viscosity, high thermal stability, wide liquid range and tunable solvent properties. In electrochemistry, the performance of an electrochemical system is dependent on the properties of the interface at the IL/electrode. This review presents the surface electrochemistry in ILs, and the interfacial structures of IL/electrode and heterogeneous electron-transfer kinetics are detailed. Finally, the updated researches on the electrochemical applications of ILs such as electrode deposition, electrosynthesis, electrocatalysis, electrochemical biosensing, electrochemical capacitor and lithium batteries are demonstrated.

引用

页码：1685 / 1697

页数：13

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