Ortho- and para-substituted Hoveyda-Grubbs carbenes. An improved synthesis of highly efficient metathesis initiators

被引：73

作者：

Bujok, R

Bieniek, M

Masnyk, M

Michrowska, A

Sarosiek, A

Stepowska, H

Arlt, D

Grela, K

机构：

[1] LIGAND Chem GmbH, D-32657 Lemgo, Germany

[2] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[3] Univ Cologne, Inst Organ Chem, D-50939 Cologne, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 20期

关键词：

D O I：

10.1021/jo049222w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel highly efficient and general route to various 3- and 5-substituted 2-alkoxystyrenes, required for the preparation of Hoveyda-Grubbs catalysts, is described.

引用

页码：6894 / 6896

页数：3

共 56 条

[41]

Schuster M, 1997, ANGEW CHEM INT EDIT, V36, P2037

[42] POLYSTYRENE-SUPPORTED RHCL3 QUATERNARY AMMONIUM ION-PAIR AS A LONG-LIVED, EFFICIENT AND RECYCLABLE CATALYST [J].

SETTYFICHMAN, M ;

BLUM, J ;

SASSON, Y ;

EISEN, M .

TETRAHEDRON LETTERS, 1994, 35 (05) :781-784

[43] The development of L2X2Ru=CHR olefin metathesis catalysts:: An organometallic success story [J].

Trnka, TM ;

Grubbs, RH .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (01) :18-29

[44] Ruthenium-mediated isomerization and ring-closing metathesis: Versatile syntheses of 6-, 7- and 8-membered benzo-fused heterocycles [J].

van Otterlo, WAL ;

Pathak, R ;

de Koning, CB .

SYNLETT, 2003, (12) :1859-1861

[45] Synthesis of coumarins by ring-closing metathesis using Grubbs' catalyst [J].

Van, TN ;

Debenedetti, S ;

De Kimpe, N .

TETRAHEDRON LETTERS, 2003, 44 (22) :4199-4201

[46] Chiral Ru-based complexes for asymmetric olefin metathesis: Enhancement of catalyst activity through steric and electronic modifications [J].

Van Veldhuizen, JJ ;

Gillingham, DG ;

Garber, SB ;

Kataoka, O ;

Hoveyda, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (41) :12502-12508

[47]

Wakamatsu H, 2002, ANGEW CHEM INT EDIT, V41, P2403, DOI 10.1002/1521-3773(20020703)41:13<2403::AID-ANIE2403>3.0.CO

[48]

2-F

[49] THE ORTHO-CLAISEN REARRANGEMENT .1. THE EFFECT OF SUBSTITUENTS ON THE REARRANGEMENT OF ALLYL PARA-X-PHENYL ETHERS [J].

WHITE, WN ;

GWYNN, D ;

SCHLITT, R ;

GIRARD, C ;

FIFE, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (13) :3271-3277

[50] Olefin metathesis in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate using a recyclable Ru catalyst: Remarkable effect of a designer ionic tag [J].

Yao, QW ;

Zhang, YL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (29) :3395-3398

← 1 2 3 4 5 6 →